Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate
Identifieur interne : 001153 ( Main/Exploration ); précédent : 001152; suivant : 001154Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate
Auteurs : A. S. Antsyshkina [Russie] ; G. G. Sadikov [Russie] ; T. V. Koksharova [Ukraine] ; I. S. Gritsenko [Ukraine] ; V. S. Sergienko [Russie]Source :
- Russian Journal of Inorganic Chemistry [ 0036-0236 ] ; 2009-08-01.
Abstract
Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.
Url:
DOI: 10.1134/S003602360908021X
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000B06
- to stream Istex, to step Curation: 000B06
- to stream Istex, to step Checkpoint: 000271
- to stream Main, to step Merge: 001163
- to stream Main, to step Curation: 001153
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title><author><name sortKey="Antsyshkina, A S" sort="Antsyshkina, A S" uniqKey="Antsyshkina A" first="A. S." last="Antsyshkina">A. S. Antsyshkina</name></author><author><name sortKey="Sadikov, G G" sort="Sadikov, G G" uniqKey="Sadikov G" first="G. G." last="Sadikov">G. G. Sadikov</name></author><author><name sortKey="Koksharova, T V" sort="Koksharova, T V" uniqKey="Koksharova T" first="T. V." last="Koksharova">T. V. Koksharova</name></author><author><name sortKey="Gritsenko, I S" sort="Gritsenko, I S" uniqKey="Gritsenko I" first="I. S." last="Gritsenko">I. S. Gritsenko</name></author><author><name sortKey="Sergienko, V S" sort="Sergienko, V S" uniqKey="Sergienko V" first="V. S." last="Sergienko">V. S. Sergienko</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:0C6DD162FAA3DD8229C38F6B2E5D125D48DCE1A0</idno><date when="2009" year="2009">2009</date><idno type="doi">10.1134/S003602360908021X</idno><idno type="url">https://api.istex.fr/ark:/67375/VQC-N2SN5R8W-R/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">000B06</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000B06</idno><idno type="wicri:Area/Istex/Curation">000B06</idno><idno type="wicri:Area/Istex/Checkpoint">000271</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000271</idno><idno type="wicri:doubleKey">0036-0236:2009:Antsyshkina A:synthesis:crystal:and</idno><idno type="wicri:Area/Main/Merge">001163</idno><idno type="wicri:Area/Main/Curation">001153</idno><idno type="wicri:Area/Main/Exploration">001153</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title><author><name sortKey="Antsyshkina, A S" sort="Antsyshkina, A S" uniqKey="Antsyshkina A" first="A. S." last="Antsyshkina">A. S. Antsyshkina</name><affiliation wicri:level="3"><country xml:lang="fr">Russie</country><wicri:regionArea>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow</wicri:regionArea><placeName><settlement type="city">Moscou</settlement><region>District fédéral central</region></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Russie</country></affiliation></author><author><name sortKey="Sadikov, G G" sort="Sadikov, G G" uniqKey="Sadikov G" first="G. G." last="Sadikov">G. G. Sadikov</name><affiliation wicri:level="3"><country xml:lang="fr">Russie</country><wicri:regionArea>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow</wicri:regionArea><placeName><settlement type="city">Moscou</settlement><region>District fédéral central</region></placeName></affiliation></author><author><name sortKey="Koksharova, T V" sort="Koksharova, T V" uniqKey="Koksharova T" first="T. V." last="Koksharova">T. V. Koksharova</name><affiliation wicri:level="1"><country xml:lang="fr">Ukraine</country><wicri:regionArea>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa</wicri:regionArea><wicri:noRegion>Odessa</wicri:noRegion></affiliation></author><author><name sortKey="Gritsenko, I S" sort="Gritsenko, I S" uniqKey="Gritsenko I" first="I. S." last="Gritsenko">I. S. Gritsenko</name><affiliation wicri:level="1"><country xml:lang="fr">Ukraine</country><wicri:regionArea>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa</wicri:regionArea><wicri:noRegion>Odessa</wicri:noRegion></affiliation></author><author><name sortKey="Sergienko, V S" sort="Sergienko, V S" uniqKey="Sergienko V" first="V. S." last="Sergienko">V. S. Sergienko</name><affiliation wicri:level="3"><country xml:lang="fr">Russie</country><wicri:regionArea>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow</wicri:regionArea><placeName><settlement type="city">Moscou</settlement><region>District fédéral central</region></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j">Russian Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Russ. J. Inorg. Chem.</title><idno type="ISSN">0036-0236</idno><idno type="eISSN">1531-8613</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2009-08-01">2009-08-01</date><biblScope unit="volume">54</biblScope><biblScope unit="issue">8</biblScope><biblScope unit="page" from="1310">1310</biblScope><biblScope unit="page" to="1315">1315</biblScope></imprint><idno type="ISSN">0036-0236</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0036-0236</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.</div></front></TEI><affiliations><list><country><li>Russie</li><li>Ukraine</li></country><region><li>District fédéral central</li></region><settlement><li>Moscou</li></settlement></list><tree><country name="Russie"><region name="District fédéral central"><name sortKey="Antsyshkina, A S" sort="Antsyshkina, A S" uniqKey="Antsyshkina A" first="A. S." last="Antsyshkina">A. S. Antsyshkina</name></region><name sortKey="Antsyshkina, A S" sort="Antsyshkina, A S" uniqKey="Antsyshkina A" first="A. S." last="Antsyshkina">A. S. Antsyshkina</name><name sortKey="Sadikov, G G" sort="Sadikov, G G" uniqKey="Sadikov G" first="G. G." last="Sadikov">G. G. Sadikov</name><name sortKey="Sergienko, V S" sort="Sergienko, V S" uniqKey="Sergienko V" first="V. S." last="Sergienko">V. S. Sergienko</name></country><country name="Ukraine"><noRegion><name sortKey="Koksharova, T V" sort="Koksharova, T V" uniqKey="Koksharova T" first="T. V." last="Koksharova">T. V. Koksharova</name></noRegion><name sortKey="Gritsenko, I S" sort="Gritsenko, I S" uniqKey="Gritsenko I" first="I. S." last="Gritsenko">I. S. Gritsenko</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001153 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001153 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Sante
|area= H2N2V1
|flux= Main
|étape= Exploration
|type= RBID
|clé= ISTEX:0C6DD162FAA3DD8229C38F6B2E5D125D48DCE1A0
|texte= Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate
}}
| This area was generated with Dilib version V0.6.33. |  |